- PII
- S30346088S0023119325040027-1
- DOI
- 10.7868/S3034608825040027
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 59 / Issue number 4
- Pages
- 201-206
- Abstract
- The effect of an additional cyano group in A-π-D dyes on optical, electrochemical, and radical polymerization initiating properties was demonstrated using anthracene-containing di- and tricyanoethylenes. It is shown that the transition from the di- to the tricyanoethylene derivative leads to a shift in the reduction potential by 0.47 V to the anodic region, a bathochromic shift of the long-wave absorption band from λmax = 427 nm to λmax = 525 nm in acetonitrile, and also to an increase in the initiation efficiency (maximum rate) of the polymerization of dimethacrylate OKM-2 under the action of LED@405 nm radiation by more than 5 times.
- Keywords
- красители арилтрицианоэтилены фотоинициатор фотополимеризация циклическая вольтамперометрия
- Date of publication
- 01.04.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 14
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